Asymmetric catalytic oxidation

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Asymmetric catalytic oxidation is a technique of oxidizing various substrates to give an enantiopure product using a catalyst.

[edit] Reactions

Jacobsen epoxidation of alkenes using manganese-salen complex and NaOCl
Sharpless epoxidation of allyl alcohols using titanium isopropoxide, diethyl tartrate, and t-butyl hydroxyperoxide
Sharpless asymmetric dihydroxylation of alkenes using dihydroquinine or dihydroquinidine ligands on an osmium metal center
Sharpless oxyamination
Shi epoxidation of alkenes using oxone and a fructose-derived chiral catalyst
Sulfonyloxaziridine enolate oxidation

[edit] References

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Please help improve this article by adding citations to reliable sources. Unverifiable material may be challenged and removed. (October 2007)

v • d • e Concepts in asymmetric synthesis

Nomenclature	Chirality, Stereocenter, Stereoisomer, Enantiomer, Diastereomer, Meso compound, Planar chirality, Chiral ligand, Axial chirality

Analysis	Optical rotation, Enantiomeric excess, Diastereomeric excess, Chiral derivitizing agents

Chiral resolution	Crystallization, Kinetic resolution, Chiral column chromatography, Diastereomeric recrystallization

Reactions	Asymmetric induction, Chiral pool synthesis, Chiral auxiliaries, Asymmetric catalytic reduction, Asymmetric catalytic oxidation, Organocatalysis, Biocatalysis

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